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Polycarbonates from renewable hydrocarbons

Polycarbonates from renewable hydrocarbons 1700 1266 Tecnon OrbiChem

It’s no secret that plant-based polycarbonate (PC) can be problematic. Not only does the plastic demonstrate complex technical properties, developing alternative chemical intermediates with the performance potential of petrochemical-based PCs can be a time-consuming process.

The wider polymer industry is already beginning to shift towards renewable carbon feedstocks such as biomass and COto reduce GHG emissions – driven by incentives and legislative penalties.

But we are also seeing more traditional producers of polycarbonates use waste carbon feedstock and/or the mass balance approach to bring certified renewable products made from biobased hydrocarbons to market.

 


‘If crude oil values remain persistently high, it is possible that biobased plastics will become increasingly competitive

Jennifer Hawkins, Tecnon OrbiChem Business Manager


‘Consumers are becoming increasingly environmentally savvy in their buying habits,’ says Tecnon OrbiChem Business Manager Jennifer Hawkins. ‘…But even more so in the automobile sector, where polycarbonate features heavily.’

‘As sales of electric cars continue to grow in a bid to meet cleaner air targets, more focus is being drawn on the materials being used to make them. It defies logic that the world continues to burn fossil fuels while trying to make green, environmentally friendly vehicles.

‘Until now, the cost of high performing biomaterials has limited their use in car production, but if crude oil values remain persistently high, it is possible that biobased plastics will become increasingly competitive, and viable for large scale industrial production use.’

Image shows a schematic diagram of the commercial polycarbonate value chain including chemicals that can be swapped for renewable feedstocks

Class: high heat polymers

An unusual and useful class of high heat polymers, polycarbonates (PC) demonstrate toughness and optical clarity. The most-used polycarbonate is produced by condensation polymerisation using Bisphenol A (BPA) along with either carbonyl chloride – also known as phosgene – or diphenyl carbonate.

Increasingly however, polycarbonates are being made with diphenyl carbonate – which removes the poisonous gas phosgene from the process. The phosgene free diphenyl carbonate (DPC) process – also known as the melt process – is cost-effective. Commercialised by Asahi Kasei in partnership with CHIMEI Corp, the pair opened a plant in Taiwan in 2002. Asahi started developing its non-phosgene aromatic for PC production 50 years ago.

CO2 copolymerisation

Aliphatic polycarbonates are synthesised by the copolymerisation of CO2 and propylene oxide – or other epoxides. It’s a process that has been commercialised but on a limited scale only.

Asahi reacts ethylene oxide with COto yield ethylene carbonate, then reacts that with methanol to give dimethyl carbonate (DMC) and monoethylene glycol. It isn’t alone in laying claim to this CO2-based DMC technology but other producers use propylene oxide, or synthesise propylene carbonate instead of ethylene carbonate before reacting with phenol.

Aromatic versus aliphatic…

When it comes to CO2-based PCs, it’s the aromatic variety that remains among the most available. But aliphatic polycarbonates (APC) – polypropylene carbonate (PPC) and polyethylene carbonate (PEC) – are increasingly available. Fast-approaching a century in existence, APCs were first manufactured by a DuPont lab around the 1930s.

PPC is synthesised from direct copolymerisation of CO2 and propylene oxide. It is said to have good barrier properties and can be used in food packaging applications

PEC uses an ethylene oxide feedstock. Because it is extrudable, it can be a suitable barrier film for multilayer construction. In terms of its end of life profile, PEC decomposes completely above 200oC and biodegrades in specific conditions.

The German research organisation the nova-Institute has reported PEC and PPC-based products to demonstrate 50% weight for aliphatic-type polymers.

High molecular mass aliphatic PCs

Ideal for injection moulding, high molecular mass aliphatic PCs have been developed. In these materials, starch-derived diol isosorbide replaces BPA. Mitsubishi Chemical Corporation developed its biobased PC DurabioTM using Roquette’s isosorbide.

In 2021, Samyang Innochem – a subsidiary of South Korea-based PC producer Samyang Group – announced construction was underway for a 1000 ktpa isosorbide plant in Gunsan, Jeollabuk-do Province, China. The company’s intent was to incorporate the biobased intermediate into its PC manufacturing.

Renewable tech on the rise

UK-based bioplastic startup Teysha Technologies developed a new biobased polycarbonate platform called AggiePol based on polyhydroxyl monomers – for example saccharides and quinic acid.

The transformations of these polyhydroxyl monomers can produce a wide range of linear and hyperbranched polymers and copolymers. Based on a plug-and-play system, the biopolymer can be tuned physically, mechanically and chemically as well as its degradation rate to suit the needs of its intended applications.

And Sabic’s LexanTM PC engineering thermoplastic resin – produced at its Cartagena, Spain, PC plant – uses certified renewable feedstock. The Saudi Arabia-headquartered company also produces mass balanced-based benzene at its steam cracker in Europe. Sabic’s process combines UPM’s renewable BioVerno bio-naphtha with fossil-based naphtha with the biobased benzene then used to produce phenol for PC feedstock. For each kilogram of PC produced based on certified renewable feedstock, around 61% of CO2 emission is reduced, Sabic claims.

Covestro has enlisted the help of Neste to replace the several thousand tons of fossil- based raw materials in its polycarbonates with Neste’s renewable hydrocarbons – biobased naphtha and bio-propane. The company markets a PC made from biobased phenol and makes PC grades from post-consumer recycled content.

With traditional chemicals producers and startups increasingly moving into the biobased space, plastics are set to become more sustainable in the future.

Tecnon OrbiChem provides insight, analysis, data and commentary on technologies emerging in the biomaterials sector.

new statista graph

Source: Statista/Covestro

This blog post was inspired by Doris de Guzman’s white paper Developing renewable polycarbonates – A balancing act.

Biopolymer specialist works with NIAB to tackle plastic pollution

Biopolymer specialist works with NIAB to tackle plastic pollution 700 336 Agronomist Arable Farmer

Biopolymer innovator Teysha Technologies has joined NIAB to research, test and develop bioplastics for the agricultural industry in the UK. The opportunity will allow Teysha to expand as the start up further commercialises in the UK, utilising the Eastern Agritech Innovation Hub near Cambridge. The Hub will be the focal point for developing and testing new sustainable materials and bioplastics to tackle growing plastic pollution as well as investigating waste feedstock options within British agricultural operations.

The first innovation to be delivered from the new Teysha laboratory will be a series of new polyester composite materials. Their purpose will be to replace some products that are currently based on petrochemical plastics, as well as improve the biodegradability of existing bioplastics such as polylactic acid. Unlike other polymer manufacturing processes, the synthesis of Teysha’s materials generates zero chemical by-products for disposal. Its properties make it susceptible to microbial breakdown, a desirable benefit for applications like packaging.

Teysha’s new polyester composites show promise as plastic alternatives across industries like agriculture and horticulture. For example, British gardeners go through 500 million plastic plant pots a year that are either incinerated or sent to landfills. On average they take an estimated 450 years to degrade and in the process may release toxic additives, dyes and microplastics into the environment. To address this, Teysha is targeting the development of alternatives using polyester composites. The goal is to prototype alternative options that provide additional plant nourishment while also having the ability to either biodegrade or be composted.

“This opportunity to work with the NIAB will allow us to further develop innovative, sustainable materials that can replace harmful plastics in industries like agriculture, as well as examine waste feedstocks for our range of biopolymers.” Said Matthew Stone, Managing Director of Teysha Technologies. “Working with such an important UK institution will also accelerate commercialisation in the UK.”

Teysha Technologies was established to solve the problems surrounding the production and use of plastics. In partnership with Texas A&M University, Teysha have developed novel second generation bioplastics based on sugar polycarbonates. Now, Teysha is extending its commercial operations to the UK where it is establishing a laboratory facility and a relationship with the NIAB.

The NIAB Group is the UK’s fastest-growing crop science organisation, addressing the challenges of food security, climate change and sustainable development in agriculture. The group works with local and national businesses at the hub to carry out commercial scale pilot studies that aid the development of the agricultural and horticultural industries in the UK.

To find out more about Teysha Technologies and its research into tuneable biodegradable biopolymers, visit the Teysha Technologies website.

The science of solving plastic pollution

The science of solving plastic pollution 1486 814 Packaging News

Fund biopolymer research, not fracking to end climate change

Fund biopolymer research, not fracking to end climate change 720 412 Energy Live News

The report by the changemakers helps to highlight the dangers of global warming and calls for leading businesses to take responsibility for contributing to the climate crisis.

Matthew Stone, Managing Director at Teysha Technologies, a biopolycarbonate research platform, shares how investing in biodegradable polymer substitutes could lead to the end of single-use plastics for good.

According to National Geographic, the Great Pacific Garbage Patch, which spans from the west coast of North America to Japan, contains 1.8 trillion plastic pieces. While oil and gas goliaths such as Sinopec and ExxonMobil are thought to produce more than 5% of the worlds single-use plastics. Banking giants HSBC and Barclays Bank are now being held accountable for lending over $3 billion each to producers of virgin polymer.

These companies must take responsibility for their colossal plastic waste footprints and start to invest in cheaper, more durable, and genuinely sustainable, greener alternatives. The question is, how can this be achieved?

Looking for Liquid Gold

Matthew Stone of Teysha Technologies says: “It is evident that plastic production damages our environment, so why do we continue to produce it? The simple answer is that it is low-cost, durable, and malleable, making it a suitable material for use in industrial and consumer products.

Sadly, all these alleged positives equal a negative, and that’s the fact that it doesn’t degrade naturally. Plastic can take an unbelievable timeframe to degrade of its own accord, certainly not in our lifetimes without the help of greenhouse gas-producing industrial catalysts and releasing harmful chemical pollutants.”

Every stage of the plastic lifecycle contributes considerably to global warming and the climate crisis. For example, fracking leaks thousands of tonnes of harmful gases into the atmosphere every day. According to National Geographic, 540,000 tonnes of methane is produced in the North Texas Barnett Shale region alone every year. This is the equivalent of 46 million tonnes of carbon dioxide being released into the environment.

Matthew Stone says: “At present, the fracked oil to make plastic is only at 14%; this is expected to continue to rise over the coming decades due to our reliance on the material. To make a difference, companies must focus on less destructive materials such as biodegradable and sustainable polymers, which can serve the same purpose but are far less damaging to the environment than traditional plastic.”

Fund Research, Not Fracking

Image: Pexels

Investing funds into research to help drive change is the answer to zero-waste plastic and a greener, safer future for us all. If the global banks invested even half of their funding into green initiatives, we would be further along in the fight against global warming. Thankfully, companies like Teysha Technologies are making landmark breakthroughs in viable plastic substitutes. Thanks to funding and research into developing biodegradable biopolymers, the research is delivering excellent results.

Teysha Technologies developed a platform where modified natural monomers, co-monomers and additives can combine to produce versatile, tunable materials comparable to traditional plastic. The platform uses various natural components, so the strength, thermal stability and degradation rates can all be controlled according to the application.

Many petrochemical-derived polycarbonates reach versatility through molar mass control, crystallinity and blending with other potentially toxic petrochemicals. The residual materials can remain in the environment for over 450 years, which can cause irreparable damage to organisms and their ecosystems. Diverting the funding from virgin plastic production and instead toward biodegradable biopolymer production, it could be possible to reverse the damage caused by climate change.

The companies named in the Plastic Waste Makers Index Report should lead the charge on these changes. If each one of them were to stop their drilling and redirect that destructive energy into the search for sustainable plastics, the world could one day become the healthier, greener carbon-neutral place we know it could be.

Teysha Technologies have created a patented, renewable, fully biodegradable plastic substitute, using waste from landfills to create polymers for hundreds of different applications.

About Teysha Technologies and Matthew Stone

As Managing Director, Matthew Stone works with a team of specialists at Teysha Technologies, who after more than a decade of research, have managed to create and develop Teysha’s unique solutions to plastic pollution.

The platform developed by Teysha and its team of globally renowned research scientists and the best commercialisation specialists in the UK, creates a range of polymers that fulfil the criteria of sustainability. Sectors such as packaging, medical equipment and construction can benefit from Teysha’s innovative technology, which produces environmentally friendly plastics as a viable, practical alternative to polycarbonates.

Partnership set to tackle microplastics in additives

Partnership set to tackle microplastics in additives 900 469 Process and Control Today
Biopolymer specialist to begin work with major manufacturer to develop sustainable alternative to microplastic additives for waxes, coatings, cosmetics and more ~

Biopolymer specialist Teysha Technologies has partnered with a major North American multinational additives manufacturer to begin joint testing and optimisation on a range of Teysha’s materials with a focus on developing alternatives to petroleum-based microplastics. The agreement will see the company begin application testing of Teysha Technologies’ second generation natural environmentally friendly biopolymers “AggiePol” and newly developed polymer lines.

Although some details of the agreement must remain undisclosed for commercial reasons, Teysha Technologies will work with the North American additives manufacturer on the potential to replace microplastics in a wide variety of real-world applications such as dyes, paints, inks, exfoliants, emulsions, waxes, lubricants, coatings and glosses among others. This will also tie in with Teysha’s continuing work with global cosmetics customers to develop sustainable replacements for microplastics in their product lines.

The company has been focused on expanding its technology platform, offering a range of polymers with multiple applications and solutions to industry depending on end-use requirements for specific product lines.

“We’ve known since 2018 that 13m tonnes of plastic reach our oceans each year and more recently that microplastics ingested by marine life are already entering the commercial food supply,” said Matthew Stone, Managing Director of Teysha Technologies. “This partnership represents our continued commitment to focus on developing earth-friendly and natural alternatives to eliminate microplastics from our waterways.”

Earlier this month, the European Union and other countries called for negotiations towards a legally-binding agreement to reduce plastic pollution, including the microplastics infesting oceans and waterways. Ministers attending a conference in Geneva, hosted by the UN Environment programme UNEP, were presented with a draft resolution stressing the urgent need to address the global crisis. UNEP has warned that “our planet is drowning in plastic pollution,” with the world today producing some 300m tonnes of plastic waste every year.

Following years of research, development and testing, Teysha Technologies’ biopolymer offers a viable substitute for petroleum-based polycarbonates. In Teysha’s plug and play technology, the monomers and comonomers, the natural building blocks that make up conventional plastic, are derived from natural sources like starches and agricultural waste products instead of hydrocarbon-based petrochemicals.

In the last few months Teysha has made advances to its original AggiePol bioplastic platform, through the development of a series of materials that exhibit tuneable thermal properties.

“AggiePol now provides for variable solubilities, thermal transition temperatures and mechanical behaviours,” explained Professor Karen Wooley, Chief Technology Officer at Teysha Technologies. “This allows the materials to be used as additives or neat plastics in applications ranging from additives, personal care and cosmetic products to personal protective equipment, plastic packaging and engineering plastics.

“This means we can tune the biopolymer according to individual application requirements to operate and then break down under specific environmental and thermal conditions, a critical benefit compared with conventional plastics, that can persist in the environment for thousands of years.”

To find out more about how to replace microplastics with sustainable biopolymers, visit www.teyshatech.co.uk.

Could a natural material replace plastic?

Could a natural material replace plastic? 2048 1505 Industry Asia

Teysha Technologies, manufacturers of sustainable bioplastic AggiePol®, has created an infographic to show how its next generation of bioplastic can replace existing petroleum-based plastics. With CO2 emissions to grow by more than 2.75 billion tonnes by 2050, the burden that manufacturing plastics has on our environment is starting to be of concern.

The Centre for International Environmental Law estimates that only one per cent of the 359 million tonnes of plastic produced each year are biodegradable. This is despite the media’s efforts to portray the ugly truth of beaches strewn with bags and bottles, and ocean life trapped by plastic rings from an eight-pack of lager. Less considered, however, is the impact of petroleum-based plastic production on the environment.

Oil and gas industries use fossil fuels such as ethylene and propylene, which release toxic gas and do not degrade. To tackle this, fuel industries created poly(butylene succinate), a biodegradable ‘eco alternative’. However, its status as being eco-friendly is debatable because of its petrochemical precursors.

“The trouble with bioplastic is that it traditionally lacks the strength, toughness and longevity of conventional plastic” explains Dr Ashlee Jahnke. “Alternatives derived from corn or sugarcane quickly fell out of favour because they are between 20 and 50 per cent more costly to produce, and only degrade under certain conditions.”

“Often, bioplastics still need industrial composting conditions, oxygen and microorganisms to biodegrade efficiently. In an ideal world this would not be an issue, but the UK doesn’t have the infrastructure in place to process bioplastics in a cost-effective way”

Some of the world’s most renown food and beverage companies started experimenting with plant-based bottles, using bioethanol from renewable sources in place of fossil fuels, which, on the surface seemed a great idea. However, it sparked ethical concerns about diverting food, such as corn, crop to make plastic alternatives. Researchers also unearthed that the material degraded in the same way as traditional plastics and therefore not a sustainable alternative.

Low oil prices and a lack of political support globally has slowed progress in the bioplastics industry. Now more than ever, the world faces increased financial pressures because of the pandemic and attentions have been temporarily turned away from the global plastics crisis. Teysha see this as an opportunity for improvement.

AggiePol® uses natural-product based building blocks to create bio-polymers which react and behave similarly to conventional plastics. Bio-polymers often have higher chemical diversity than typical hydrocarbons, meaning their physical, mechanical and chemical properties can be finely tuned. This allows developers to manipulate degradation rates, while boasting strength, toughness and durability.

As a second-generation bioplastic, AggiePol® is capable of degradation, and can regenerate the natural-product building blocks. Not only could it replace ethylene-derived non-biodegradable plastics, but it could replace existing petroleum-based polycarbonates. Plenty of applications can benefit from this – from food packaging, cosmetics and pharmaceuticals to medical-grade implantation and textiles.

What is the solution to plastic pollution?

What is the solution to plastic pollution? 1536 727 Pollution Solutions Online

“People and the planet are only as healthy as the ecosystems we depend on.” This is a statement to encourage ecosystem restoration published by the United Nations Environment Programme (UNEP). But ecosystem restoration is more than a pathway to achieving climate goals. Here Duncan Clark, head of operations at biopolymer researcher Teysha Technologies, explains how we can take steps in restoring ecosystems by terminating the use of Earth’s biggest polluter, plastic.

The WWF describes plastic pollution as one of the most visible symptoms of the environmental crisis, damaging natural habitats and threatening wildlife. In fact, the Geneva Environment Network estimates that the cumulative production of plastic surpassed eight billion metric tons worldwide in 2020 and is expected to increase in the coming decades.

The images we see in the media of litter-strewn beaches and marine life tangled up in single-use plastic bags are powerful conversation starters, but they don’t represent the entire problem. Plastic is harmful from the point of manufacture and even with more robust recycling policies, the plastic crisis will persist into the future if we can’t source a sustainable alternative.

To understand the extent of this issue, we must dig deeper into how plastic is produced.

Plastic’s ugly truths

Most plastic production requires a core ingredient: crude oil dug deep from the Earth’s crust. The seismic vibrations caused by oil extraction is enough to disrupt some habitats. But when you factor in the threat of oil spills and the infrastructure needed to transport resources in-land, thousands of species have been displaced to accommodate demand for crude oil.
It may not seem much, but five per cent of all global crude oil extracted is used for the manufacturing of plastics. This actually equates to approximately 35m barrels per year.

Plastic production is also extremely energy intensive, consuming 2000 times the amount of energy it takes to treat and distribute tap water. It also generates harmful pollutants that damage the Earth’s atmosphere and leach into our land and water systems.

The carbon emissions from producing plastic are threatening thousands of species who are struggling to adapt to rapidly changing environmental temperatures. National Public Radio (NPR) estimates that carbon emissions from plastic production could amount to 56 gigatons between now and 2050.

Finally, the products made from plastic pose an even bigger threat to our ecosystems. One single-use plastic bottle, whose contents may take minutes to consume, will persist in the environment anywhere from 450 years to several thousand years.

The result is that there are now some 80,000 tonnes of plastic — the equivalent weight of 500 jumbo jets — in the Great Pacific Garbage Patch alone, according to The Ocean Clean Up. Once broken down into microplastic particles, these are consumed by marine life, only to work their way back through the food chain and end up on our plates.

The evidence is clear that plastic is a cause for concern, but it’s convenience cannot be understated. The good news is that there is now a viable alternative that means we can feasibly outlaw traditional plastic for good.

Solving the polymer puzzle

Teysha Technologies has developed a polymer platform using sustainable feedstocks to generate Earth-friendly polycarbonate materials. This plug-and-play system incorporates natural monomers and co-monomers, rather than hydrocarbons from crude oil, formulated from starches or agricultural waste.

A major benefit of this is that the resulting material’s physical, mechanical and chemical properties can be tuned to fit specific applications. Even the polycarbonate’s degradation rates are tuneable. Food packaging, for example, is often disposed of after a single use, so it could be tuned to break down quicker in an environment with sufficient moisture.

A common problem with traditional bioplastics, despite being composed of ‘greener’ materials, is that they still need industrial catalysts and the right microbial conditions to degrade. Most countries simply don’t have the infrastructure to facilitate this.

By considering the impact of each stage in the lifecycle of plastic on ecosystems, we can start to transition from petrochemical-based plastics towards truly natural, harmless materials.

Teysha Technologies: The road to biomaterials

Teysha Technologies: The road to biomaterials 1440 540 Sustainability Magazine
Duncan Clark, head of operations at Teysha Technologies, discusses how biopolymers will reduce plastic production in the automotive industry

There are approximately 960,000 Ford Fiesta’s registered on Britain’s roads. Each of these cars requires 100 gallons or more of crude oil to manufacture the plastic in the car’s interior, bodywork, crumple zones and engine components. What’s more, this plastic will still be around long after the car has reached the end of its useful lifetime. Here Duncan Clark, head of operations at biopolymer research company Teysha Technologies, explains how automakers can overcome this problem by switching to tuneable bioplastics.

With many carmakers switching to EV production, significant gains are being made in making the automotive industry more sustainable. However, the 120 kilograms of plastic going into manufacturing every car will outlive the vehicle by about 380 years. This poses the question: is the investment in the car worth the environmental cost of producing this much plastic?

Plastics are used by carmakers because they are lightweight, versatile and durable. For example, the plastics in a Ford Fiesta will be used to improve passenger and driver comfort and enhance the safety of the vehicle. Plastic also reduces vehicle weight, improving the overall fuel economy. But this does not counteract the resource-intensive process of manufacturing plastic, and carmakers should now be investigating sustainable polymer alternatives.

Polyester in car interiors

Plastics Europe estimates that twelve to fifteen per cent of a car’s weight is plastic. Some plastic components are built to last the lifetime of the car, including the textiles, dashboard, interior trim and exterior bodywork such as the bumpers. Others are designed to be replaced, including the floor mats and windscreen wipers. Mats, for example, are composed of polyester fibres and will be replaced after a few years of wear and tear.

However, polyester production is highly polluting and uses approximately 330 million barrels of oil per year. Common Objective also predicts that 14.2 kilograms of carbon dioxide is produced per kilogram of polyester. If up to 25 kilograms of polyester is used in a Ford Fiesta’s interior, that equates to 355 kilograms of carbon dioxide produced in making one car’s textiles.

It is understandable why polyester has become a popular choice for car interiors. Seatbelts, for example, are also composed of petroleum-derived fibres and help to protect passengers from serious injury. Safety is unquestionably important, so efforts to find sustainable bioplastics, which meet safety standards, should be a priority.

Plastic bodywork

Plastic composites, like polypropylene, are used in car crumple zones because they absorb more energy on impact than metals. This means that the driver of a modern car with a plastic crumple zone is much more likely to survive a Road Traffic Accident (RTA), than an older car with metal crumple zones.

However, a recent study in Nature Communications estimates that 100,000 metric tonnes of microplastics make their way from crumple zones and vehicle exteriors into our water systems every year. This may be from general wear-and-tear, illegal scrapping and damage leftover by RTAs. To put this into perspective, this is the equivalent weight of all 960,000 British-registered Ford Fiesta’s surviving in our ecosystems for hundreds of years.

Global carmakers are now working on solutions to alleviate plastic pollution, such as manufacturing vehicles using recycled plastics. But will these efforts go far enough, or is it time to stop producing plastic altogether?

Why recycling doesn’t go far enough

Global automotive companies have been experimenting with recycled plastic in their car designs for many years now. Nissan, for example, manufactures the LEAF electric vehicle, which is made from 25 per cent recycled materials. 60 per cent of the LEAF’s interior is derived from PET plastic bottles, making it a definite step in the right direction for the automotive industry.

To further this effort, in 2020, students at the Eindhoven University of Technology, Netherlands, proved that manufacturing a vehicle from 100% recycled plastic and household waste is possible. Plastic bottles and broken household appliances were used to flesh out the car body, windows and interior, most of these fished out of the ocean or dug up from landfill.

Solutions like the ones employed by Nissan and the Eindhoven students are certainly commendable. But recycling infrastructure in many countries is simply inadequate and would not be able to generate the materials needed for large-scale car manufacturing. Efforts should now be focussed on improving recycling practices in tandem with halting plastic production altogether. This is achievable by switching to using durable, versatile and plastic-like biopolymers.

A biopolymer future

Biodegradable biopolymers, such as those developed by Teysha Technologies, are showing promise as plastic alternatives. This technology may eventually help steer the industry away from non-renewable, petroleum-based plastics.

The past five years have seen Teysha achieve a landmark breakthrough in its second-generation biopolymer. Made from natural feedstocks, such as starches and agricultural waste, this versatile polymer can be physically, mechanically and chemically tuned to meet the needs of the automotive industry.

Crucially, these biopolymers overcome many of the challenges of existing biopolymers, like the fact that their hydrolytic breakdown can be controlled — and unlike conventional biopolymers, they can be made to biodegrade in nature, and without the use of industrial catalysts.

All plastic elements of a car could make use of biodegradable biopolymers, from carpets to crumples zones. If every automotive manufacturer were to make this transition, the resource-intensive refining of plastics would soon become obsolete.

To find out more about Teysha Technologies, click here

The road to biomaterials

The road to biomaterials 1500 1125 Interplas Insights

There are approximately 960,000 Ford Fiesta’s registered on Britain’s roads. Each of these cars requires 100 gallons or more of crude oil to manufacture the plastic in the car’s interior, bodywork, crumple zones and engine components. What’s more, this plastic will still be around long after the car has reached the end of its useful lifetime. Here Duncan Clark, head of operations at biopolymer research company Teysha Technologies, explains how automakers can overcome this problem by switching to tuneable bioplastics.

With many carmakers switching to EV production, significant gains are being made in making the automotive industry more sustainable. However, the 120 kilograms of plastic going into manufacturing every car will outlive the vehicle by about 380 years. This poses the question: is the investment in the car worth the environmental cost of producing this much plastic?

Plastics are used by carmakers because they are lightweight, versatile and durable. For example, the plastics in a Ford Fiesta will be used to improve passenger and driver comfort and enhance the safety of the vehicle. Plastic also reduces vehicle weight, improving the overall fuel economy. But this does not counteract the resource-intensive process of manufacturing plastic, and carmakers should now be investigating sustainable polymer alternatives.

Polyester in car interiors

Plastics Europe estimates that twelve to fifteen per cent of a car’s weight is plastic. Some plastic components are built to last the lifetime of the car, including the textiles, dashboard, interior trim and exterior bodywork such as the bumpers. Others are designed to be replaced, including the floor mats and windscreen wipers. Mats, for example, are composed of polyester fibres and will be replaced after a few years of wear-and-tear.

However, polyester production is highly polluting and uses approximately 330 million barrels of oil per year. Common Objective also predicts that 14.2 kilograms of carbon dioxide is produced per kilogram of polyester. If up to 25 kilograms of polyester is used in a Ford Fiesta’s interior, that equates to 355 kilograms of carbon dioxide produced in making one car’s textiles.

It is understandable why polyester has become a popular choice for car interiors. Seatbelts, for example, are also composed of petroleum-derived fibres and help to protect passengers from serious injury. Safety is unquestionably important, so efforts to find sustainable bioplastics, which meet safety standards, should be a priority.

Plastic bodywork

Plastic composites, like polypropylene, are used in car crumple zones because they absorb more energy on impact than metals. This means that the driver of a modern car with a plastic crumple zone is much more likely to survive a Road Traffic Accident (RTA), than an older car with metal crumple zones.

However, a recent study in Nature Communications estimates that 100,000 metric tonnes of microplastics make their way from crumple zones and vehicle exteriors into our water systems every year. This may be from general wear-and-tear, illegal scrapping and damage left over by RTAs. To put this into perspective, this is the equivalent weight of all 960,000 British-registered Ford Fiesta’s surviving in our ecosystems for hundreds of years.

Global carmakers are now working on solutions to alleviate plastic pollution, such as manufacturing vehicles using recycled plastics. But will these efforts go far enough, or is it time to stop producing plastic altogether?

Why recycling doesn’t go far enough

Global automotive companies have been experimenting with recycled plastic in their car designs for many years now. Nissan, for example, manufactures the LEAF electric vehicle, which is made from 25 per cent recycled materials. 60 per cent of the LEAF’s interior is derived from PET plastic bottles, making it a definite step in the right direction for the automotive industry.

To further this effort, in 2020, students at the Eindhoven University of Technology, Netherlands, proved that manufacturing a vehicle from 100 per cent recycled plastic and household waste was possible. Plastic bottles and broken household appliances were used to flesh out the car body, windows and interior, most of these fished out of the ocean or dug up from landfill.

Solutions like the ones employed by Nissan and the Eindhoven students are certainly commendable. But recycling infrastructure in many countries is simply inadequate and would not be able generate the materials needed for large-scale car manufacturing. Efforts should now be focussed on improving recycling practices in tandem with halting plastic production altogether. This is achievable by switching to using durable, versatile and plastic-like biopolymers.

A biopolymer future

Biodegradable biopolymers, such as those developed by Teysha Technologies, are showing promise as plastic alternatives. This technology may eventually help steer the industry away from non-renewable, petroleum-based plastics.

The past five years have seen Teysha achieve a landmark breakthrough in its second-generation biopolymer. Made from natural feedstocks, such as starches and agricultural waste, this versatile polymer can be physically, mechanically and chemically tuned to meet the needs of the automotive industry.

Crucially, these biopolymers overcome many of the challenges of existing biopolymers, like the fact that their hydrolytic breakdown can be controlled — and unlike conventional biopolymers, they can be made to biodegrade in nature, and without the use of industrial catalysts.

All plastic elements of a car could make use of biodegradable biopolymers, from carpets to crumples zones. If every automotive manufacturer were to make this transition, the resource-intensive refining of plastics would soon become obsolete.

Biopolymer specialist Teysha Technologies urges cosmetic companies to move to green polymers

Biopolymer specialist Teysha Technologies urges cosmetic companies to move to green polymers 767 776 Renewable Carbon News

Teysha Technologies to discuss the use of its biodegradable biopolymers as an additive to reduce environmentally damaging microplastics

A specialist in the development of biodegradable polymers from natural sources is calling on the cosmetics industry to reduce its use of conventional polymers, which contribute towards global plastic pollution. The company, Teysha Technologies, is in talks with several global cosmetic brands to discuss the use of its biodegradable biopolymers as an additive to reduce environmentally damaging microplastics — and is now urging other companies to follow suit.

Despite legislation around the use of plastics in cosmetic products tightening in recent years, the industry still relies heavily on their use as additives. In products such as moisturising lotions, microplastics — polymer fragments that measure less than five millimetres in size — are commonly used as emulsifiers and viscosity regulators.

When such products are washed away, the microplastic fragments are introduced into the environment where they can remain for hundreds of years or be consumed by animals and enter the food chain. According to numbers presented by the UK Government in 2018, a single shower using a shower gel containing microplastics can lead to as many as 100,000 microbeads entering the ocean. Although exfoliating plastic microbeads have been banned in cosmetic products in the UK since 2018, microplastics from other sources are still present.

Teysha Technologies argues that there is little reason for cosmetic manufacturers to still be using environmentally harmful polymers, because greener alternatives are now available.

“Polymers play an important role in most cosmetic products, from stabilising formulations to helping products remain on the skin for longer,” explained Matthew Stone, managing director of Teysha Technologies. “However, there is no reason why many of those polymers need to be unsustainable or environmentally damaging.

“Teysha has been leading research into the development of biopolymers that are completely biodegradable, while still having all the properties needed to suit a range of uses. This led us to develop a tuneable biopolymer that we can tailor to specific applications. Cosmetics is one of these areas and we are working with a global cosmetic manufacturer looking into the use of our polymer platform to support the move away from environmentally damaging products.

“In the coming years, legislation will only continue to tighten around plastic use. The European cosmetics industry is already facing the issues this can present due to the imminent rollout of the European Chemicals Agency’s (ECHA’s) proposed microplastic restrictions in early 2022. Making the swap to biodegradable, environmentally benign alternatives now will save the regulatory cost and complications of product reformulation.”

In 2019, the ECHA proposed new restrictions on the use of ‘intentionally added microplastics’. Although there are some exemptions to the proposed restrictions, the proposal would mean significant reformulation costs for cosmetic manufacturers. Industry association Cosmetics Europe has been critical of the impact the restrictions would impose on the industry, claiming the proposal would be “extremely disproportionate in its effects” on cosmetics manufacturers.

Teysha Technologies developed a natural polycarbonate platform that can create fully biodegradable substitutes for existing petroleum-based plastics. The bioplastic, AggiePol, is derived from sustainable feedstocks and can be physically, mechanically and chemically tuned to suit the needs of its intended application, with degradation time also being tuneable. This means it can be made suitable for use not only in cosmetic products as a functional plastic, but also in cosmetic packaging.

Source

Bioplastics MAGAZINE, 2020-12-03.

Supplier

Cosmetics Europe
European Chemicals Agency (ECHA)
Teysha Technologies

Source: Renewable Carbon News